Search results for "piano-stool geometry"

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Crystal structure of chlorido(2-{1-[2-(4-chlorophenyl)hydrazin-1-ylidene-κN]ethyl}pyridine-κN)(η5-pentamethylcyclopentadienyl)rhodium(III) chloride

2015

The title compound, [Rh(η5-C5Me5)Cl(C13H12ClN3)]Cl, is chiral at the metal and crystallizes as a racemate. Upon coordination, the hydrazinyl­idene­pyridine ligand is non-planar, an angle of 54.42 (7)° being observed between the pyridine ring and the aromatic ring of the [2-(4-chloro­phen­yl)hydrazin-1-yl­idene]ethyl group.

crystal structureNanotechnologyCrystal structureRing (chemistry)Medicinal chemistryResearch CommunicationsMetalpenta­methyl­cyclo­penta­dien­yllcsh:Chemistrychemistry.chemical_compoundPyridinepiano-stool geometryGeneral Materials SciencepentamethylcyclopentadienylEthyl grouprhodium(III) complexN—H⋯Cl hydrogen bondHydrogen bondLigandGeneral ChemistryRhodium(III) chlorideN—H...Cl hydrogen bondCondensed Matter Physicschemistrylcsh:QD1-999visual_artvisual_art.visual_art_mediumActa Crystallographica Section E: Crystallographic Communications
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